Negima!: Magister Negi Magi, Volume 19
Volume 19 has a lot of good stuff, pre-staging the forthcoming Magic World arc, exploring Asuna, and picking up some small stories for different characters as well.
The first half of the manga is dedicated to Asuna. For starters, we get to see how Nagi and Ala Rubra first met Asuna during the war on the Magic World and rescued her (learning her real name
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Episode: Mahou Sensei Negima! Episode 19